working on it. Still looking for the volume of primary containment in any one of the units. Not sure why that is as difficult to find as it is.
You need to step back for a moment and look at the PWR vs the BWR.
The BWR is very close to being a closed system. You have a bunch of water in containment that is used to feed the ECCS system and quench the steam coming out of the SRVs. The isolation condenser can be used as a way to reject decay heat to atmosphere but this is not a design feature used at every plant.
PWR behave more like an open system as long as they have a feed source and water to pump into the steam generators. One pound of water will absorb lots of energy by becoming a pound of steam. This energy gets rejected to atmosphere easily by simply dumping it to atmosphere. The SGs being able to reject steam to atmosphere is a design feature that every PWR has.
The way that I would attack this problem would be to look at the UFSAR of your PWR and see how how much inventory the CST has. I would then break the time after the start of the accident event into blocks of time (30 minutes per block of time?). Figure out the decay heat rate for each block of time based on time after shutdown and how much inventory is needed to remove all that heat. This will give you an approximation of how long the steam driven AFP will be able to supply water to the steam generators. Figure out what the decay heat rate of the reactor is at the time that the CST is expected to be depleted and then treat the PWR as a closed system like the BWR.
The UFSAR also has total volume of CTMT. You can also look at chapter 15 of the UFSAR to maybe give you some ideas on how to attack this problem.
I would also make some basic assumptions to make it more simple.
1) I would expect that the steam generators would lose coupling to the primary even if you had an infinite supply of water to feed the SGs. Without the ability to make up water to the RCS from leaks through the seals you will eventually start running low on RCS inventory. The question that needs to be answered is; will I run out of water in the CST first or will I run out of inventory in the RCS needed to have adequate natural circulation cooling?
2) Assume that the the SGs remain intact (no SGTR). Figure out how much inventory you have in CTMT that is not inside the SGs from the original RCS inventory (include the Core Flood Tanks) and any inventory that was able to be gravity dumped in before CTMT pressure gets above the shutoff head of your water source.
Based on the answers to your assumptions; you have a total mass of water inside CTMT, the average starting temperature of that water, and the decay heat generation rate. You then need to pretend that CTMT is a homogeneous system. You should then be able to figure out the rate that it is pressurizing and then extrapolate from there when CTMT reaches the design pressure.